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Energy () is the quantitative property that is transferred to a or to a , recognizable in the performance of work and in the form of and . Energy is a —the law of conservation of energy states that energy can be converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the (J).

Forms of energy include the of a moving object, the stored by an object (for instance due to its position in a field), the stored in a solid object, associated with chemical reactions, the carried by electromagnetic radiation, the contained within a thermodynamic system, and associated with an object's . These are not mutually exclusive.

All constantly take in and release energy. The Earth's and processes are driven primarily by .


Forms
The total energy of a can be subdivided and classified into , , or combinations of the two in various ways. Kinetic energy is determined by the movement of an object – or the composite motion of the object's components – while reflects the potential of an object to have motion, generally being based upon the object's position within a field or what is stored within the field itself.

While these two categories are sufficient to describe all forms of energy, it is often convenient to refer to particular combinations of potential and kinetic energy as its own form. For example, the sum of translational and rotational kinetic and potential energy within a system is referred to as mechanical energy, whereas nuclear energy refers to the combined potentials within an atomic nucleus from either the or the , among other examples.

+Some forms of energy (that an object or system can have as a measurable property)
(2025). 9780080531359, Elsevier. .
(2025). 9789333221832, Technical Publications. .
!scope="col"
Type of energy !scope="col"Description


History
The word energy derives from the , which possibly appears for the first time in the work of in the 4th century BC. In contrast to the modern definition, energeia was a qualitative philosophical concept, broad enough to include ideas such as happiness and pleasure.

In the late 17th century, Gottfried Leibniz proposed the idea of the , or living force, which defined as the product of the mass of an object and its velocity squared; he believed that total vis viva was conserved. To account for slowing due to friction, Leibniz theorized that thermal energy consisted of the motions of the constituent parts of matter, although it would be more than a century until this was generally accepted. The modern analog of this property, , differs from vis viva only by a factor of two. Writing in the early 18th century, Émilie du Châtelet proposed the concept of conservation of energy in the marginalia of her French language translation of Newton's Principia Mathematica, which represented the first formulation of a conserved measurable quantity that was distinct from , and which would later be called "energy".

In 1807, Thomas Young was possibly the first to use the term "energy" instead of vis viva, in its modern sense.

(1998). 9780226764207, The University of Chicago Press.
Gustave-Gaspard Coriolis described "" in 1829 in its modern sense, and in 1853, William Rankine coined the term "". The law of conservation of energy was also first postulated in the early 19th century, and applies to any . It was argued for some years whether heat was a physical substance, dubbed the , or merely a physical quantity, such as . In 1845 James Prescott Joule discovered the link between mechanical work and the generation of heat.

These developments led to the theory of conservation of energy, formalized largely by William Thomson () as the field of .

(2025). 9781930832022, Microanalytix. .
Thermodynamics aided the rapid development of explanations of chemical processes by , Josiah Willard Gibbs, , and others.
(2025). 9780122511004, Academic Press. .
It also led to a mathematical formulation of the concept of by Clausius
(2025). 9781583946985, North Atlantic Books. .
and to the introduction of laws of by Jožef Stefan. According to Noether's theorem, the conservation of energy is a consequence of the fact that the laws of physics do not change over time.
(2025). 9780701637774, John Wiley & Sons Australia Limited.
Thus, since 1918, theorists have understood that the law of conservation of energy is the direct mathematical consequence of the translational symmetry of the quantity conjugate to energy, namely time.
(2025). 9781581126457, Universal-Publishers. .

Albert Einstein's 1905 theory of special relativity showed that corresponds to an equivalent amount of . This means that rest mass can be converted to or from equivalent amounts of (non-material) forms of energy, for example, kinetic energy, potential energy, and electromagnetic . When this happens, rest mass is not conserved, unlike the total mass or total energy. All forms of energy contribute to the total mass and total energy. Thus, conservation of energy ( total, including material or rest energy) and conservation of mass ( total, not just rest) are one (equivalent) law. In the 18th century, these had appeared as two seemingly-distinct laws.

(2025). 9789814525619, World Scientific. .
(2025). 9783759712189, BoD – Books on Demand. .

The first evidence of quantization in atoms was the observation of in light from the sun in the early 1800s by Joseph von Fraunhofer and William Hyde Wollaston. The notion of quantized energy levels was proposed in 1913 by Danish physicist in the of the atom. The modern quantum mechanical theory giving an explanation of these energy levels in terms of the Schrödinger equation was advanced by Erwin Schrödinger and Werner Heisenberg in 1926.

(2013). 9780841227163, American Chemical Society.
Noether's theorem shows that the symmetry of this equation is equivalent to a conservation of probability.
(2025). 9781541702974, PublicAffairs. .
At the quantum level, mass-energy interactions are all subject to this principle.
(2025). 9780486151854, Courier Corporation. .
During wave function collapse, the conservation of energy does not hold at the local level, although statistically the principle holds on average for sufficiently large numbers of collapses. Conservation of energy does apply during wave function collapse in H. Everett's many-worlds interpretation of quantum mechanics.


Units of measure
In dimensional analysis, the of energy are given by: Work = Force × Distance = M L2 T−2, with the fundamental dimensions of Mass M, Length L, and time T.
(2025). 9781483187006, Elsevier. .
In the International System of Units (SI), the unit of energy is the . It is a derived unit that is equal to the energy expended, or work done, in applying a force of one newton through a distance of one metre.
(2025). 9788120336537, PHI Learning Pvt. Ltd.. .

The SI unit of power, defined as energy per unit of time, is the , which is one joule per second. Thus, a (kWh), which can be realized as the energy delivered by one kilowatt of power for an hour, is equal to 3.6 million joules. The CGS energy unit is the and the imperial and US customary unit is the .

(2025). 9780444538055, Newnes. .

Other energy units such as the , , thermodynamic and BTU are used in specific areas of science and commerce.

(2025). 9780857292445, Springer Science & Business Media. .
(2025). 9780873354356, Society for Mining, Metallurgy & Exploration. .


Scientific use

Classical mechanics
In classical mechanics, energy is a conceptually and mathematically useful property, as it is a conserved quantity. Several formulations of mechanics have been developed using energy as a core concept.

Work, a function of energy, is force times distance.

(2025). 9780387218519, Springer Science & Business Media. .

W = \int_C \mathbf{F} \cdot \mathrm{d} \mathbf{s}

This says that the work (W) is equal to the of the F along a path C; for details see the article. Work and thus energy is . For example, consider a ball being hit by a bat. In the , the bat does no work on the ball. But, in the reference frame of the person swinging the bat, considerable work is done on the ball.

(2025). 9780444639868, Elsevier. .

The total energy of a system is sometimes called the Hamiltonian, after William Rowan Hamilton. The classical equations of motion can be written in terms of the Hamiltonian, even for highly complex or abstract systems. These classical equations have direct analogs in nonrelativistic quantum mechanics.

(2025). 9783662047507, Springer Science & Business Media. .

Another energy-related concept is called the Lagrangian, after Joseph-Louis Lagrange. This formalism is as fundamental as the Hamiltonian, and both can be used to derive the equations of motion or be derived from them. It was invented in the context of classical mechanics, but is generally useful in modern physics. The Lagrangian is defined as the kinetic energy minus the potential energy. Usually, the Lagrange formalism is mathematically more convenient than the Hamiltonian for non-conservative systems (such as systems with friction).

Noether's theorem (1918) states that any differentiable symmetry of the action of a physical system has a corresponding conservation law. Noether's theorem has become a fundamental tool of modern theoretical physics and the calculus of variations. A generalisation of the seminal formulations on constants of motion in Lagrangian and Hamiltonian mechanics (1788 and 1833, respectively), it does not apply to systems that cannot be modeled with a Lagrangian;

(2025). 9781040300732, CRC Press. .
for example, dissipative systems with continuous symmetries need not have a corresponding conservation law.


Chemistry
In the context of chemistry, is an attribute of a substance as a consequence of its atomic, molecular, or aggregate structure. Since a chemical transformation is accompanied by a change in one or more of these kinds of structure, it is usually accompanied by a decrease, and sometimes an increase, of the total energy of the substances involved. Some energy may be transferred between the surroundings and the reactants in the form of heat or light; thus the products of a reaction have sometimes more but usually less energy than the reactants. A reaction is said to be exothermic or if the final state is lower on the energy scale than the initial state; in the less common case of endothermic reactions the situation is the reverse.See chemical change in:
(2025). 9781119267843, John Wiley & Sons. .

Chemical reactions are usually not possible unless the reactants surmount an energy barrier known as the activation energy. The speed of a chemical reaction (at a given temperature  T) is related to the activation energy  E by the Boltzmann population factor eE/ kT; that is, the probability of a molecule to have energy greater than or equal to  E at a given temperature  T. This exponential dependence of a reaction rate on temperature is known as the Arrhenius equation. The activation energy necessary for a chemical reaction can be provided in the form of thermal energy.

(2025). 9781118698709, John Wiley & Sons. .


Biology
In biology, energy is an attribute of all biological systems, from the biosphere to the smallest living organism. It enables the growth, development, and functioning of a biological cell or in an organism. All living creatures rely on an external source of energy to be able to grow and reproduce – radiant energy from the Sun in the case of green plants and chemical energy (in some form) in the case of animals. Energy provided through cellular respiration is stored in nutrients such as (including sugars), , and by cells.
(2025). 9780128093320, Academic Press.

Sunlight's radiant energy is captured by plants as chemical potential energy in , when carbon dioxide and water (two low-energy compounds) are converted into carbohydrates, lipids, proteins, and oxygen.

(2025). 9781000218848, CRC Press.
Release of the energy stored during photosynthesis as heat or light may be triggered suddenly by a spark in a forest fire, or it may be made available more slowly for animal or human metabolism when organic molecules are ingested and is triggered by action.
(2025). 9780262300582, MIT Press. .


Humans
The basal metabolism rate measures the expenditure per unit time by animals at rest. In other words it is the energy required by body organs to perform normally. For humans, metabolic equivalent of task (MET) compares the energy expenditure per unit mass while performing a physical activity, relative to a baseline. By convention, this baseline is 3.5 mL of oxygen consumed per kg per minute, which is the energy consumed by a typical individual when sitting quietly.

For example, if our bodies run (on average) at 80 watts, then a light bulb running at 100 watts is running at 1.25 human equivalents (100 ÷ 80) i.e. 1.25 H-e. For a difficult task of only a few seconds' duration, a person can put out thousands of watts, many times the 746 watts in one official horsepower. For tasks lasting a few minutes, a fit human can generate perhaps 1,000 watts. For an activity that must be sustained for an hour, output drops to around 300; for an activity kept up all day, 150 watts is about the maximum. The human equivalent assists understanding of energy flows in physical and biological systems by expressing energy units in human terms: it provides a "feel" for the use of a given amount of energy.Bicycle calculator – speed, weight, wattage etc. .
     

The daily recommended for a human adult are taken as food molecules, mostly carbohydrates and fats. Only a tiny fraction of the original chemical energy is used for work:These examples are solely for illustration, as it is not the energy available for work which limits the performance of the athlete but the power output (in case of a sprinter) and the force (in case of a weightlifter).

gain in kinetic energy of a sprinter during a 100 m race: 4 kJ
gain in gravitational potential energy of a 150 kg weight lifted through 2 metres: 3 kJ
daily food intake of a normal adult: 6–8 MJ
It would appear that living organisms are remarkably inefficient (in the physical sense) in their use of the energy they receive (chemical or radiant energy); most manage higher efficiencies.

In growing organisms the energy that is converted to heat serves a vital purpose, as it allows the organism's tissue to be highly ordered with regard to the molecules it is built from. The second law of thermodynamics states that energy (and matter) tends to become more evenly spread out across the universe: to concentrate energy (or matter) in one specific place, it is necessary to spread out a greater amount of energy (as heat) across the remainder of the universe ("the surroundings"). are another example of highly ordered systems that exist in nature: in this case too, the order is associated with the transfer of a large amount of heat (known as the ) to the surroundings. Simpler organisms can achieve higher energy efficiencies than more complex ones, but the complex organisms can occupy that are not available to their simpler brethren. The conversion of a portion of the chemical energy to heat at each step in a metabolic pathway is the physical reason behind the pyramid of biomass observed in . As an example, to take just the first step in the : of the estimated 124.7 Pg/a of carbon that is by , 64.3 Pg/a (52%) are used for the metabolism of green plants, i.e. reconverted into carbon dioxide and heat.


Cell metabolism
Multicellular organisms such as humans have cell forms that are classified as . These cells include an called the that generates for the rest of the hosting cell. Ninety percent of the oxygen intake by humans is utilized by the , especially for nutrient processing.
(2025). 9781119436829, John Wiley & Sons. .
The molecule adenosine triphosphate (ATP) is the primary energy transporter in living cells, providing an energy source for cellular processes. It is continually being broken down and synthesized as a component of cellular respiration.
(2025). 9780199609499, OUP Oxford. .

Two examples of nutrients consumed by animals are (C6H12O6) and (C57H110O6). These food molecules are oxidized to and water in the mitochondria:

(2025). 9781284591606, Jones & Bartlett Learning.
C6H12O6 + 6O2 -> 6CO2 + 6H2O C57H110O6 + (81 1/2) O2 -> 57CO2 + 55H2O and some of the energy is used to convert ADP into ATP:

The rest of the chemical energy of the nutrients are converted into heat: the ATP is used as a sort of "energy currency", and some of the chemical energy it contains is used for other when ATP reacts with OH groups and eventually splits into ADP and phosphate (at each stage of a metabolic pathway, some chemical energy is converted into heat).


Earth sciences
In geology, continental drift, , , and are phenomena that can be explained in terms of energy transformations in the Earth's interior, while phenomena like wind, rain, , snow, lightning, , and are all a result of energy transformations in our brought about by .

Sunlight is the main input to Earth's energy budget which accounts for its temperature and climate stability, after accounting for interaction with the atmosphere.

(2025). 9781108615815, Cambridge University Press. .
Sunlight may be stored as gravitational potential energy after it strikes the Earth, as (for example when) water evaporates from oceans and is deposited upon mountains (where, after being released at a hydroelectric dam, it can be used to drive turbines or generators to produce electricity).
(2025). 9781447123712, Springer Science & Business Media. .
An example of a solar-mediated weather event is a hurricane, which occurs when large unstable areas of warm ocean, heated over months, suddenly give up some of their thermal energy to power a few days of violent air movement.
(2025). 9780128149256, Elsevier.

In a slower process, radioactive decay of atoms in the core of the Earth releases heat, which supplies more than half of the planet's internal heat budget. In the present day, this production was primarily driven by the decay of Uranium-235, Potassium-40, and Thorium-232 some time in the past.

(2025). 9780198945437, Oxford University Press. .
This thermal energy drives and may lift mountains, via . This slow lifting represents a kind of gravitational potential of the thermal energy, which may later be transformed into active kinetic energy during landslides, after a triggering event. Earthquakes also release stored elastic potential energy in rocks, a store that has been produced ultimately from the same radioactive heat sources. Thus, according to present understanding, familiar events such as landslides and earthquakes release energy that has been stored as potential energy in the Earth's gravitational field or elastic strain (mechanical potential energy) in rocks.
(2025). 9781921536731, ANU E Press. .
Prior to this, they represent release of energy that has been stored in heavy atoms since the collapse of long-destroyed supernova stars (which created these atoms).
(2025). 9780306469275, Springer Science & Business Media. .

Early in a planet's history, the accretion process provides impact energy that can partially or completely melt the body. This allows a planet to become differentiated by chemical element. Chemical phase changes of minerals during formation provide additional internal heating. Over time the internal heat is brought to the surface then radiated away into space, cooling the body. Accreted radiogenic heat sources settle toward the core, providing thermal energy to the planet on a geologic time scale.

(2025). 9780080494586, Elsevier. .
Ongoing provides a persistent internal energy source for planets like and .


Cosmology
In cosmology and astronomy the phenomena of , , , , and are the universe's highest-output energy transformations of matter. All phenomena (including solar activity) are driven by various kinds of energy transformations. Energy in such transformations is either from gravitational collapse of matter (usually molecular hydrogen) into various classes of astronomical objects (stars, , etc.), or from nuclear fusion (of lighter elements, primarily hydrogen).
(2012). 9789401005401, Kluwer Academic Publishers.

The of hydrogen in the Sun also releases another store of potential energy which was created at the time of the . At that time, according to theory, space expanded and the universe cooled too rapidly for hydrogen to completely fuse into heavier elements. This meant that hydrogen represents a store of potential energy that can be released by fusion. Such a fusion process is triggered by heat and pressure generated from gravitational collapse of hydrogen clouds when they produce stars, and some of the fusion energy is then transformed into sunlight.

(1988). 9780226724577, University of Chicago Press. .

The accretion of matter onto a is a very efficient means of generating energy from gravitational potential. This behavior is responsible for some of the universe's brightest persistent energy sources.

(1996). 9780521550918, CUP Archive. .
The is a theoretical method by which energy could be extracted from a rotating black hole. Hawking radiation is the emission of black-body radiation from a black hole, which results in a steady loss of mass and rotational energy. As the object evaporates, the temperature of this radiation is predicted to increase, speeding up the process.
(2025). 9781594544750, Nova Publishers. .


Quantum mechanics
In quantum mechanics, energy is defined in terms of the energy operator (Hamiltonian) as a time derivative of the . The Schrödinger equation equates the energy operator to the full energy of a particle or a system. Its results can be considered as a definition of measurement of energy in quantum mechanics. The Schrödinger equation describes the space- and time-dependence of a slowly changing (non-relativistic) of quantum systems. The solution of this equation for a bound system is discrete (a set of permitted states, each characterized by an ) which results in the concept of .
(2025). 9781420027716, CRC Press. .

In the solution of the Schrödinger equation for any oscillator (vibrator) and for electromagnetic waves in a vacuum, the resulting energy states are related to the frequency by the : E = h\nu, where h is the and \nu the frequency. In the case of an electromagnetic wave these energy states are called quanta of light or . For , the de Broglie relation yields p = h \nu, where p is the .

(2025). 9781000161526, CRC Press. .


Relativity
When calculating kinetic energy ( to accelerate a from zero to some finite speed) relativistically – using Lorentz transformations instead of Newtonian mechanics – Einstein discovered an unexpected by-product of these calculations to be an energy term which does not vanish at zero speed. He called it : energy which every massive body must possess even when being at rest. The amount of energy is directly proportional to the mass of the body:
(2025). 9789811904974, Springer Nature. .

E_0 = m_0 c^2 , where

  • m0 is the of the body,
  • c is the speed of light in vacuum,
  • E_0 is the rest energy.

For example, consider annihilation, in which the rest energy of these two individual particles (equivalent to their rest mass) is converted to the radiant energy of the photons produced in the process. In this system the and (electrons and positrons) are destroyed and changed to non-matter (the photons). However, the total mass and total energy do not change during this interaction. The photons each have no rest mass but nonetheless have radiant energy which exhibits the same inertia as did the two original particles. This is a reversible process – the inverse process is called – in which the rest mass of the particles is created from a sufficiently energetic photon near a nucleus.

(2025). 9781000383911, CRC Press. .

In general relativity, the stress–energy tensor serves as the source term for the gravitational field, in rough analogy to the way mass serves as the source term in the non-relativistic Newtonian approximation.

Energy and mass are manifestations of one and the same underlying physical property of a system. This property is responsible for the inertia and strength of gravitational interaction of the system ("mass manifestations"),

(1998). 9780521634205, Cambridge University Press. .
and is also responsible for the potential ability of the system to perform work or heating ("energy manifestations"), subject to the limitations of other physical laws.

In classical physics, energy is a scalar quantity, the canonical conjugate to time. In special relativity energy is also a scalar (although not a but a time component of the energy–momentum 4-vector).

(1973). 9780716703440, W. H. Freeman.
In other words, energy is invariant with respect to rotations of , but not invariant with respect to rotations of (= ).


Transformation
+Some forms of of energy ("energy in transit") from one object or system to another ! Type of transfer process!! Description
equal amount of thermal energy in transit spontaneously towards a lower- object
Workequal amount of energy in transit due to a displacement in the direction of an applied
Transfer of materialequal amount of energy carried by that is moving from one system to another

Energy may be transformed between different forms at various efficiencies. Devices that usefully transform between these forms are called . Examples of transducers include a battery (from to ), a dam (from gravitational potential energy to the of water spinning the blades of a , and ultimately to through an electric generator), and a (from heat to work).

(2025). 9783319203553, Springer.
(2025). 9781447132653, Springer Science & Business Media. .

Examples of energy transformation include generating from heat energy via a steam turbine, or lifting an object against gravity using electrical energy driving a crane motor. Lifting against gravity performs mechanical work on the object and stores gravitational potential energy in the object. If the object falls to the ground, gravity does mechanical work on the object which transforms the potential energy in the gravitational field to the kinetic energy released as heat on impact with the ground.

(2025). 9781483140308, Elsevier. .
The Sun transforms nuclear potential energy to other forms of energy; its total mass does not decrease due to that itself (since it still contains the same total energy even in different forms) but its mass does decrease when the energy escapes out to its surroundings, largely as .
(2025). 9781108835817, Cambridge University Press. .

There are strict limits to how efficiently heat can be converted into work in a cyclic process, e.g. in a heat engine, as described by Carnot's theorem and the second law of thermodynamics.

(2025). 9783031349508, Springer Nature. .
However, some energy transformations can be quite efficient.
(1992). 9780226870298, University of Chicago Press. .
The direction of transformations in energy (what kind of energy is transformed to what other kind) is often determined by (equal energy spread among all available degrees of freedom) considerations. In practice all energy transformations are permitted on a sufficiently small scale, but certain larger transformations are highly improbable because it is statistically unlikely that energy or matter will randomly move into more concentrated forms or smaller spaces.
(2025). 9780471495734, John Wiley & Sons. .

Energy transformations in the universe over time are characterized by various kinds of potential energy, that has been available since the , being "released" (transformed to more active types of energy such as kinetic or radiant energy) when a triggering mechanism is available.

(2025). 9780231521680, Columbia University Press. .
Familiar examples of such processes include , a process ultimately using the gravitational potential energy released from the gravitational collapse of to "store" energy in the creation of heavy isotopes (such as and ), and , a process in which energy is released that was originally stored in these heavy elements, before they were incorporated into the Solar System and the Earth.
(2025). 9781317227137, Routledge.
This energy is triggered and released in nuclear or in civil nuclear power generation. Similarly, in the case of a chemical explosion, chemical potential energy is transformed to and in a very short time.

Yet another example of energy transformation is that of a simple gravity . At its highest points the is zero and the gravitational potential energy is at its maximum. At its lowest point the is at its maximum and is equal to the decrease in . If one (unrealistically) assumes that there is no or other losses, the conversion of energy between these processes would be perfect, and the would continue swinging forever. Energy is transferred from potential energy (E_p) to kinetic energy (E_k) and then back to potential energy constantly. This is referred to as conservation of energy.

In this , energy cannot be created or destroyed; therefore, the initial energy and the final energy will be equal to each other. This can be demonstrated by the following:

The equation can then be simplified further since E_p = mgh (mass times acceleration due to gravity times the height) and E_k = \frac{1}{2} mv^2 (half mass times velocity squared). Then the total amount of energy can be found by adding E_p + E_k = E_\text{total}.


Conservation of energy and mass in transformation
Within a gravitational field, both mass and energy give rise to a measureable weight when trapped in a system with zero momentum. The formula E =  mc2, derived by (1905) quantifies this mass–energy equivalence between relativistic mass and energy within the concept of special relativity. In different theoretical frameworks, similar formulas were derived by J. J. Thomson (1881), Henri Poincaré (1900), Friedrich Hasenöhrl (1904), and others (see Mass–energy equivalence#History for further information).

Part of the rest energy (equivalent to rest mass) of may be converted to other forms of energy (still exhibiting mass), but neither energy nor mass can be destroyed; rather, both remain constant during any process. However, since c^2 is extremely large relative to ordinary human scales, the conversion of an everyday amount of rest mass from rest energy to other forms of energy (such as kinetic energy, thermal energy, or the radiant energy carried by light and other radiation) can liberate tremendous amounts of energy, as can be seen in and nuclear weapons.

(2025). 9781119800255, John Wiley & Sons. .
For example, 1 kg of rest mass equals , equivalent to 21.5 megatonnes of TNT.The energy from the rest mass is given by the mass-energy equivalence:
  • E = mc2 = 1 kg × ()2 =
  • TNT energy = †
Hence,
  • E = ()/() = 21.5 megatonnes
†:

Conversely, the mass equivalent of an everyday amount energy is minuscule. Examples of large-scale transformations between the rest energy of matter and other forms of energy are found in and . The complete conversion of matter, such as atoms, to non-matter, such as photons, occurs during interaction with .


Reversible and non-reversible transformations
Thermodynamics divides energy transformation into two kinds: reversible processes and irreversible processes. An irreversible process is one in which energy is dissipated (spread) into empty energy states available in a volume, from which it cannot be recovered into more concentrated forms (fewer quantum states), without degradation of even more energy. A reversible process is one in which this sort of dissipation does not happen. For example, conversion of energy from one type of potential field to another is reversible, as in the pendulum system described above.
(2025). 9789813226074, World Scientific Publishing Company. .

At the atomic scale, thermal energy is present in the form of motion and vibrations of individual atoms and molecules. When heat is generated, radiation excites lower energy states of these atoms and their surrounding fields. This heating process acts as a reservoir for part of the applied energy, from which it cannot be converted with 100% efficiency into other forms of energy.

(2025). 9780174387336, Nelson Thornes. .
According to the second law of thermodynamics, this heat can only be completely recovered as usable energy at the price of an increase in some other kind of heat-like disorder in quantum states.

As the universe evolves with time, more and more of its energy becomes trapped in irreversible states (i.e., as heat or as other kinds of increases in disorder). This has led to the hypothesis of the inevitable thermodynamic heat death of the universe. In this heat death the energy of the universe does not change, but the fraction of energy which is available to do work through a , or be transformed to other usable forms of energy (through the use of generators attached to heat engines), continues to decrease.

(2025). 9780429017889, CRC Press. .


Conservation of energy
The fact that energy can be neither created nor destroyed is called the law of conservation of energy. In the form of the first law of thermodynamics, this states that a 's energy is constant unless energy is transferred in or out as work or , and that no energy is lost in transfer. The total inflow of energy into a system must equal the total outflow of energy from the system, plus the change in the energy contained within the system. Whenever one measures (or calculates) the total energy of a system of particles whose interactions do not depend explicitly on time, it is found that the total energy of the system always remains constant.

While heat can always be fully converted into work in a reversible isothermal expansion of an ideal gas, for cyclic processes of practical interest in the second law of thermodynamics states that the system doing work always loses some energy as . This creates a limit to the amount of heat energy that can do work in a cyclic process, a limit called the . Mechanical and other forms of energy can be transformed in the other direction into without such limitations. The total energy of a system can be calculated by adding up all forms of energy in the system.

said during a 1961 lecture:

Most kinds of energy (with gravitational energy being a notable exception) are subject to strict local conservation laws as well. In this case, energy can only be exchanged between adjacent regions of space, and all observers agree as to the volumetric density of energy in any given space. There is also a global law of conservation of energy, stating that the total energy of the universe cannot change; this is a corollary of the local law, but not vice versa. The Laws of Thermodynamics. including careful definitions of energy, free energy, et cetera.

(1964). ((9780201021158)), Addison Wesley. ((9780201021158))

This law is a fundamental principle of physics. As shown rigorously by Noether's theorem, the conservation of energy is a mathematical consequence of translational symmetry of time, a property of most phenomena below the cosmic scale that makes them independent of their locations on the time coordinate. Put differently, yesterday, today, and tomorrow are physically indistinguishable. This is because energy is the quantity which is canonical conjugate to time. This mathematical entanglement of energy and time also results in the uncertainty principle – it is impossible to define the exact amount of energy during any definite time interval (though this is practically significant only for very short time intervals). The uncertainty principle should not be confused with energy conservation – rather it provides mathematical limits to which energy can in principle be defined and measured.

Each of the basic forces of nature is associated with a different type of potential energy, and all types of potential energy (like all other types of energy) appear as system , whenever present. For example, a compressed spring will be slightly more massive than before it was compressed. Likewise, whenever energy is transferred between systems by any mechanism, an associated mass is transferred with it.

(2025). 9783030128784, Springer. .

In quantum mechanics energy is expressed using the Hamiltonian operator. On any time scale, the uncertainty in the energy is given by

\Delta E \Delta t \ge \frac { \hbar } {2 }
which is similar in form to the Heisenberg Uncertainty Principle,
(1997). 9783642081798, Springer Berlin Heidelberg.
but not really mathematically equivalent thereto, since E and t are not dynamically conjugate variables, neither in classical nor in quantum mechanics.
(2025). 9780521877602, Cambridge University Press. .

In , this inequality permits a qualitative understanding of virtual particles, which carry . The exchange of virtual particles with real particles is responsible for the creation of all known fundamental forces (more accurately known as fundamental interactions).

(2025). 9789400724631, Springer Science & Business Media. .
are also responsible for the electrostatic interaction between (which results in Coulomb's law), for spontaneous radiative decay of excited atomic and nuclear states, for the ,
(2025). 9781439895344, CRC Press. .
for the Van der Waals force,
(2025). 9783540368076, Springer Science & Business Media. .
and some other observable phenomena.


Energy transfer

Closed systems
Energy transfer can be considered for the special case of systems which are to transfers of matter. The portion of the energy which is transferred by conservative forces over a distance is measured as the work the source system does on the receiving system. The portion of the energy which does not do work during the transfer is called .Although heat is "wasted" energy for a specific energy transfer (see: ), it can often be harnessed to do useful work in subsequent interactions. However, the maximum energy that can be "recycled" from such recovery processes is limited by the second law of thermodynamics. Energy can be transferred between systems in a variety of ways. Examples include the transmission of electromagnetic energy via photons, physical collisions which transfer ,The mechanism for most macroscopic physical collisions is actually , but it is very common to simplify the interaction by ignoring the mechanism of collision and just calculate the beginning and end result. tidal interactions,
(2025). 9781107016651, Cambridge University Press. .
and the conductive transfer of .
(2025). 9781439835166, EPFL Press. .

Energy is strictly conserved and is also locally conserved wherever it can be defined. In thermodynamics, for closed systems, the process of energy transfer is described by the first law:There are several sign conventions for this equation. Here, the signs in this equation follow the IUPAC convention.

where E is the amount of energy transferred, W  represents the work done on or by the system, and Q represents the heat flow into or out of the system. As a simplification, the heat term, Q, can sometimes be ignored, especially for fast processes involving gases, which are poor conductors of heat, or when the thermal efficiency of the transfer is high. For such adiabatic processes,

This simplified equation is the one used to define the , for example.


Open systems
Beyond the constraints of closed systems, open systems can gain or lose energy in association with matter transfer (this process is illustrated by injection of an air-fuel mixture into a car engine, a system which gains in energy thereby, without addition of either work or heat). Denoting this energy by E_\text{matter}, one may write:
(2025). 9781119500384, John Wiley & Sons. .


Thermodynamics

Internal energy
is the sum of all microscopic forms of energy of a system. It is the energy needed to create the system. It is related to the potential energy, e.g., molecular structure, crystal structure, and other geometric aspects, as well as the motion of the particles, in form of kinetic energy. Thermodynamics is chiefly concerned with changes in internal energy and not its absolute value, which is impossible to determine with thermodynamics alone.I. Klotz, R. Rosenberg, Chemical Thermodynamics – Basic Concepts and Methods, 7th ed., Wiley (2008), p. 39


First law of thermodynamics
The first law of thermodynamics asserts that the total energy of a system and its surroundings (but not necessarily thermodynamic free energy) is always conserved
(1980). 9780716710882, W. H. Freeman.
and that heat flow is a form of energy transfer. For homogeneous systems, with a well-defined temperature and pressure, a commonly used corollary of the first law is that, for a system subject only to forces and heat transfer (e.g., a cylinder-full of gas) without chemical changes, the differential change in the internal energy of the system (with a gain in energy signified by a positive quantity) is given as:
(2025). 9789811386916, Springer Nature. .

\mathrm{d}E = T\mathrm{d}S - P\mathrm{d}V\,,
where the first term on the right is the heat transferred into the system, expressed in terms of T and S (in which entropy increases and its change d S is positive when heat is added to the system), and the last term on the right hand side is identified as work done on the system, where pressure is P and volume V (the negative sign results since compression of the system requires work to be done on it and so the volume change, d V, is negative when work is done on the system).

This equation is highly specific, ignoring all chemical, electrical, nuclear, and gravitational forces, effects such as of any form of energy other than heat and PV-work. The general formulation of the first law (i.e., conservation of energy) is valid even in situations in which the system is not homogeneous. For these cases the change in internal energy of a closed system is expressed in a general form by:

\mathrm{d}E=\delta Q+\delta W
where \delta Q is the heat supplied to the system and \delta W is the work applied to the system.


Equipartition of energy
The energy of a mechanical harmonic oscillator (a mass on a spring) is alternately and . At two points in the oscillation it is entirely kinetic, and at two points it is entirely potential. Over a whole cycle, or over many cycles, average energy is equally split between kinetic and potential. This is an example of the equipartition principle: the total energy of a system with many degrees of freedom is equally split among all available degrees of freedom, on average.
(2025). 9781136672996, Garland Science. .

This principle is vitally important to understanding the behavior of a quantity closely related to energy, called . Entropy is a measure of evenness of a distribution of energy between parts of a system. When an isolated system is given more degrees of freedom (i.e., given new available that are the same as existing states), then total energy spreads over all available degrees equally without distinction between "new" and "old" degrees. This mathematical result is part of the second law of thermodynamics. The second law of thermodynamics is simple only for systems which are near or in a physical equilibrium state. For non-equilibrium systems, the laws governing the systems' behavior are still debatable. One of the guiding principles for these systems is the principle of maximum entropy production. It states that nonequilibrium systems behave in such a way as to maximize their entropy production.


See also


Notes

External links

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