Energy () is the quantitative property that is transferred to a physical body or to a physical system, recognizable in the performance of work and in the form of heat and light. Energy is a Conservation law—the law of conservation of energy states that energy can be converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J).
Forms of energy include the kinetic energy of a moving object, the potential energy stored by an object (for instance due to its position in a field), the elastic energy stored in a solid object, chemical energy associated with chemical reactions, the radiant energy carried by electromagnetic radiation, the internal energy contained within a thermodynamic system, and rest energy associated with an object's rest mass. These are not mutually exclusive.
All life constantly take in and release energy. The Earth's climate and processes are driven primarily by Solar irradiance.
While these two categories are sufficient to describe all forms of energy, it is often convenient to refer to particular combinations of potential and kinetic energy as its own form. For example, the sum of translational and rotational kinetic and potential energy within a system is referred to as mechanical energy, whereas nuclear energy refers to the combined potentials within an atomic nucleus from either the nuclear force or the weak force, among other examples.
+Some forms of energy (that an object or system can have as a measurable property) !scope="col" | Type of energy !scope="col" | Description |
In the late 17th century, Gottfried Leibniz proposed the idea of the , or living force, which defined as the product of the mass of an object and its velocity squared; he believed that total vis viva was conserved. To account for slowing due to friction, Leibniz theorized that thermal energy consisted of the motions of the constituent parts of matter, although it would be more than a century until this was generally accepted. The modern analog of this property, kinetic energy, differs from vis viva only by a factor of two. Writing in the early 18th century, Émilie du Châtelet proposed the concept of conservation of energy in the marginalia of her French language translation of Newton's Principia Mathematica, which represented the first formulation of a conserved measurable quantity that was distinct from momentum, and which would later be called "energy".
In 1807, Thomas Young was possibly the first to use the term "energy" instead of vis viva, in its modern sense. Gustave-Gaspard Coriolis described "kinetic energy" in 1829 in its modern sense, and in 1853, William Rankine coined the term "potential energy". The law of conservation of energy was also first postulated in the early 19th century, and applies to any isolated system. It was argued for some years whether heat was a physical substance, dubbed the caloric theory, or merely a physical quantity, such as momentum. In 1845 James Prescott Joule discovered the link between mechanical work and the generation of heat.
These developments led to the theory of conservation of energy, formalized largely by William Thomson (Lord Kelvin) as the field of thermodynamics. Thermodynamics aided the rapid development of explanations of chemical processes by Rudolf Clausius, Josiah Willard Gibbs, Walther Nernst, and others. It also led to a mathematical formulation of the concept of entropy by Clausius and to the introduction of laws of radiant energy by Jožef Stefan. According to Noether's theorem, the conservation of energy is a consequence of the fact that the laws of physics do not change over time.
Albert Einstein's 1905 theory of special relativity showed that Invariant mass corresponds to an equivalent amount of rest energy. This means that rest mass can be converted to or from equivalent amounts of (non-material) forms of energy, for example, kinetic energy, potential energy, and electromagnetic radiant energy. When this happens, rest mass is not conserved, unlike the total mass or total energy. All forms of energy contribute to the total mass and total energy. Thus, conservation of energy ( total, including material or rest energy) and conservation of mass ( total, not just rest) are one (equivalent) law. In the 18th century, these had appeared as two seemingly-distinct laws.
The first evidence of quantization in atoms was the observation of spectral lines in light from the sun in the early 1800s by Joseph von Fraunhofer and William Hyde Wollaston. The notion of quantized energy levels was proposed in 1913 by Danish physicist Niels Bohr in the Bohr theory of the atom. The modern quantum mechanical theory giving an explanation of these energy levels in terms of the Schrödinger equation was advanced by Erwin Schrödinger and Werner Heisenberg in 1926.
The SI unit of power, defined as energy per unit of time, is the watt, which is one joule per second. Thus, a kilowatt-hour (kWh), which can be realized as the energy delivered by one kilowatt of power for an hour, is equal to 3.6 million joules. The CGS energy unit is the erg and the imperial and US customary unit is the foot-pound.
Other energy units such as the electronvolt, food calorie, thermodynamic kilocalorie and BTU are used in specific areas of science and commerce.
Work, a function of energy, is force times distance.
This says that the work () is equal to the line integral of the force F along a path C; for details see the mechanical work article. Work and thus energy is frame dependent. For example, consider a ball being hit by a bat. In the center-of-mass reference frame, the bat does no work on the ball. But, in the reference frame of the person swinging the bat, considerable work is done on the ball.
The total energy of a system is sometimes called the Hamiltonian, after William Rowan Hamilton. The classical equations of motion can be written in terms of the Hamiltonian, even for highly complex or abstract systems. These classical equations have direct analogs in nonrelativistic quantum mechanics.
Another energy-related concept is called the Lagrangian, after Joseph-Louis Lagrange. This formalism is as fundamental as the Hamiltonian, and both can be used to derive the equations of motion or be derived from them. It was invented in the context of classical mechanics, but is generally useful in modern physics. The Lagrangian is defined as the kinetic energy minus the potential energy. Usually, the Lagrange formalism is mathematically more convenient than the Hamiltonian for non-conservative systems (such as systems with friction).
Noether's theorem (1918) states that any differentiable symmetry of the action of a physical system has a corresponding conservation law. Noether's theorem has become a fundamental tool of modern theoretical physics and the calculus of variations. A generalisation of the seminal formulations on constants of motion in Lagrangian and Hamiltonian mechanics (1788 and 1833, respectively), it does not apply to systems that cannot be modeled with a Lagrangian; for example, dissipative systems with continuous symmetries need not have a corresponding conservation law.
Chemical reactions are usually not possible unless the reactants surmount an energy barrier known as the activation energy. The speed of a chemical reaction (at a given temperature T) is related to the activation energy E by the Boltzmann population factor e− E/ kT; that is, the probability of a molecule to have energy greater than or equal to E at a given temperature T. This exponential dependence of a reaction rate on temperature is known as the Arrhenius equation. The activation energy necessary for a chemical reaction can be provided in the form of thermal energy.
Sunlight's radiant energy is captured by plants as chemical potential energy in photosynthesis, when carbon dioxide and water (two low-energy compounds) are converted into carbohydrates, lipids, proteins, and oxygen. Release of the energy stored during photosynthesis as heat or light may be triggered suddenly by a spark in a forest fire, or it may be made available more slowly for animal or human metabolism when organic molecules are ingested and catabolism is triggered by enzyme action.
For example, if our bodies run (on average) at 80 watts, then a light bulb running at 100 watts is running at 1.25 human equivalents (100 ÷ 80) i.e. 1.25 H-e. For a difficult task of only a few seconds' duration, a person can put out thousands of watts, many times the 746 watts in one official horsepower. For tasks lasting a few minutes, a fit human can generate perhaps 1,000 watts. For an activity that must be sustained for an hour, output drops to around 300; for an activity kept up all day, 150 watts is about the maximum. The human equivalent assists understanding of energy flows in physical and biological systems by expressing energy units in human terms: it provides a "feel" for the use of a given amount of energy.Bicycle calculator – speed, weight, wattage etc. .
The daily recommended for a human adult are taken as food molecules, mostly carbohydrates and fats. Only a tiny fraction of the original chemical energy is used for work:These examples are solely for illustration, as it is not the energy available for work which limits the performance of the athlete but the power output (in case of a sprinter) and the force (in case of a weightlifter).
In growing organisms the energy that is converted to heat serves a vital purpose, as it allows the organism's tissue to be highly ordered with regard to the molecules it is built from. The second law of thermodynamics states that energy (and matter) tends to become more evenly spread out across the universe: to concentrate energy (or matter) in one specific place, it is necessary to spread out a greater amount of energy (as heat) across the remainder of the universe ("the surroundings"). are another example of highly ordered systems that exist in nature: in this case too, the order is associated with the transfer of a large amount of heat (known as the lattice energy) to the surroundings. Simpler organisms can achieve higher energy efficiencies than more complex ones, but the complex organisms can occupy that are not available to their simpler brethren. The conversion of a portion of the chemical energy to heat at each step in a metabolic pathway is the physical reason behind the pyramid of biomass observed in ecology. As an example, to take just the first step in the food chain: of the estimated 124.7 Pg/a of carbon that is carbon fixation by photosynthesis, 64.3 Pg/a (52%) are used for the metabolism of green plants, i.e. reconverted into carbon dioxide and heat.
Two examples of nutrients consumed by animals are glucose (C6H12O6) and stearin (C57H110O6). These food molecules are oxidized to carbon dioxide and water in the mitochondria:
The rest of the chemical energy of the nutrients are converted into heat: the ATP is used as a sort of "energy currency", and some of the chemical energy it contains is used for other metabolism when ATP reacts with OH groups and eventually splits into ADP and phosphate (at each stage of a metabolic pathway, some chemical energy is converted into heat).
Sunlight is the main input to Earth's energy budget which accounts for its temperature and climate stability, after accounting for interaction with the atmosphere. Sunlight may be stored as gravitational potential energy after it strikes the Earth, as (for example when) water evaporates from oceans and is deposited upon mountains (where, after being released at a hydroelectric dam, it can be used to drive turbines or generators to produce electricity). An example of a solar-mediated weather event is a hurricane, which occurs when large unstable areas of warm ocean, heated over months, suddenly give up some of their thermal energy to power a few days of violent air movement.
In a slower process, radioactive decay of atoms in the core of the Earth releases heat, which supplies more than half of the planet's internal heat budget. In the present day, this radiogenic heat production was primarily driven by the decay of Uranium-235, Potassium-40, and Thorium-232 some time in the past. This thermal energy drives plate tectonics and may lift mountains, via orogenesis. This slow lifting represents a kind of gravitational potential energy storage of the thermal energy, which may later be transformed into active kinetic energy during landslides, after a triggering event. Earthquakes also release stored elastic potential energy in rocks, a store that has been produced ultimately from the same radioactive heat sources. Thus, according to present understanding, familiar events such as landslides and earthquakes release energy that has been stored as potential energy in the Earth's gravitational field or elastic strain (mechanical potential energy) in rocks. Prior to this, they represent release of energy that has been stored in heavy atoms since the collapse of long-destroyed supernova stars (which created these atoms).
Early in a planet's history, the accretion process provides impact energy that can partially or completely melt the body. This allows a planet to become differentiated by chemical element. Chemical phase changes of minerals during formation provide additional internal heating. Over time the internal heat is brought to the surface then radiated away into space, cooling the body. Accreted radiogenic heat sources settle toward the core, providing thermal energy to the planet on a geologic time scale. Ongoing sedimentation provides a persistent internal energy source for gas giant planets like Jupiter and Saturn.
The nuclear fusion of hydrogen in the Sun also releases another store of potential energy which was created at the time of the Big Bang. At that time, according to theory, space expanded and the universe cooled too rapidly for hydrogen to completely fuse into heavier elements. This meant that hydrogen represents a store of potential energy that can be released by fusion. Such a fusion process is triggered by heat and pressure generated from gravitational collapse of hydrogen clouds when they produce stars, and some of the fusion energy is then transformed into sunlight.
The accretion of matter onto a compact object is a very efficient means of generating energy from gravitational potential. This behavior is responsible for some of the universe's brightest persistent energy sources. The Penrose process is a theoretical method by which energy could be extracted from a rotating black hole. Hawking radiation is the emission of black-body radiation from a black hole, which results in a steady loss of mass and rotational energy. As the object evaporates, the temperature of this radiation is predicted to increase, speeding up the process.
In the solution of the Schrödinger equation for any oscillator (vibrator) and for electromagnetic waves in a vacuum, the resulting energy states are related to the frequency by the Planck relation: , where is the Planck constant and the frequency. In the case of an electromagnetic wave these energy states are called quanta of light or . For , the de Broglie relation yields , where is the momentum.
where
For example, consider electron–positron annihilation, in which the rest energy of these two individual particles (equivalent to their rest mass) is converted to the radiant energy of the photons produced in the process. In this system the matter and antimatter (electrons and positrons) are destroyed and changed to non-matter (the photons). However, the total mass and total energy do not change during this interaction. The photons each have no rest mass but nonetheless have radiant energy which exhibits the same inertia as did the two original particles. This is a reversible process – the inverse process is called pair creation – in which the rest mass of the particles is created from a sufficiently energetic photon near a nucleus.
In general relativity, the stress–energy tensor serves as the source term for the gravitational field, in rough analogy to the way mass serves as the source term in the non-relativistic Newtonian approximation.
Energy and mass are manifestations of one and the same underlying physical property of a system. This property is responsible for the inertia and strength of gravitational interaction of the system ("mass manifestations"), and is also responsible for the potential ability of the system to perform work or heating ("energy manifestations"), subject to the limitations of other physical laws.
In classical physics, energy is a scalar quantity, the canonical conjugate to time. In special relativity energy is also a scalar (although not a Lorentz scalar but a time component of the energy–momentum 4-vector).
Energy may be transformed between different forms at various efficiencies. Devices that usefully transform between these forms are called . Examples of transducers include a battery (from chemical energy to electric energy), a dam (from gravitational potential energy to the kinetic energy of water spinning the blades of a turbine, and ultimately to electric energy through an electric generator), and a heat engine (from heat to work).
Examples of energy transformation include generating electric energy from heat energy via a steam turbine, or lifting an object against gravity using electrical energy driving a crane motor. Lifting against gravity performs mechanical work on the object and stores gravitational potential energy in the object. If the object falls to the ground, gravity does mechanical work on the object which transforms the potential energy in the gravitational field to the kinetic energy released as heat on impact with the ground. The Sun transforms nuclear potential energy to other forms of energy; its total mass does not decrease due to that itself (since it still contains the same total energy even in different forms) but its mass does decrease when the energy escapes out to its surroundings, largely as radiant energy.
There are strict limits to how efficiently heat can be converted into work in a cyclic process, e.g. in a heat engine, as described by Carnot's theorem and the second law of thermodynamics. However, some energy transformations can be quite efficient. The direction of transformations in energy (what kind of energy is transformed to what other kind) is often determined by entropy (equal energy spread among all available degrees of freedom) considerations. In practice all energy transformations are permitted on a sufficiently small scale, but certain larger transformations are highly improbable because it is statistically unlikely that energy or matter will randomly move into more concentrated forms or smaller spaces.
Energy transformations in the universe over time are characterized by various kinds of potential energy, that has been available since the Big Bang, being "released" (transformed to more active types of energy such as kinetic or radiant energy) when a triggering mechanism is available. Familiar examples of such processes include nucleosynthesis, a process ultimately using the gravitational potential energy released from the gravitational collapse of to "store" energy in the creation of heavy isotopes (such as uranium and thorium), and nuclear decay, a process in which energy is released that was originally stored in these heavy elements, before they were incorporated into the Solar System and the Earth. This energy is triggered and released in nuclear or in civil nuclear power generation. Similarly, in the case of a chemical explosion, chemical potential energy is transformed to kinetic energy and thermal energy in a very short time.
Yet another example of energy transformation is that of a simple gravity pendulum. At its highest points the kinetic energy is zero and the gravitational potential energy is at its maximum. At its lowest point the kinetic energy is at its maximum and is equal to the decrease in potential energy. If one (unrealistically) assumes that there is no friction or other losses, the conversion of energy between these processes would be perfect, and the pendulum would continue swinging forever. Energy is transferred from potential energy () to kinetic energy () and then back to potential energy constantly. This is referred to as conservation of energy.
In this isolated system, energy cannot be created or destroyed; therefore, the initial energy and the final energy will be equal to each other. This can be demonstrated by the following:
The equation can then be simplified further since (mass times acceleration due to gravity times the height) and (half mass times velocity squared). Then the total amount of energy can be found by adding .
Part of the rest energy (equivalent to rest mass) of matter may be converted to other forms of energy (still exhibiting mass), but neither energy nor mass can be destroyed; rather, both remain constant during any process. However, since is extremely large relative to ordinary human scales, the conversion of an everyday amount of rest mass from rest energy to other forms of energy (such as kinetic energy, thermal energy, or the radiant energy carried by light and other radiation) can liberate tremendous amounts of energy, as can be seen in and nuclear weapons. For example, 1 kg of rest mass equals , equivalent to 21.5 megatonnes of TNT.The energy from the rest mass is given by the mass-energy equivalence:
Conversely, the mass equivalent of an everyday amount energy is minuscule. Examples of large-scale transformations between the rest energy of matter and other forms of energy are found in nuclear physics and particle physics. The complete conversion of matter, such as atoms, to non-matter, such as photons, occurs during interaction with antimatter.
At the atomic scale, thermal energy is present in the form of motion and vibrations of individual atoms and molecules. When heat is generated, radiation excites lower energy states of these atoms and their surrounding fields. This heating process acts as a reservoir for part of the applied energy, from which it cannot be converted with 100% efficiency into other forms of energy. According to the second law of thermodynamics, this heat can only be completely recovered as usable energy at the price of an increase in some other kind of heat-like disorder in quantum states.
As the universe evolves with time, more and more of its energy becomes trapped in irreversible states (i.e., as heat or as other kinds of increases in disorder). This has led to the hypothesis of the inevitable thermodynamic heat death of the universe. In this heat death the energy of the universe does not change, but the fraction of energy which is available to do work through a heat engine, or be transformed to other usable forms of energy (through the use of generators attached to heat engines), continues to decrease.
While heat can always be fully converted into work in a reversible isothermal expansion of an ideal gas, for cyclic processes of practical interest in the second law of thermodynamics states that the system doing work always loses some energy as waste heat. This creates a limit to the amount of heat energy that can do work in a cyclic process, a limit called the available energy. Mechanical and other forms of energy can be transformed in the other direction into thermal energy without such limitations. The total energy of a system can be calculated by adding up all forms of energy in the system.
Richard Feynman said during a 1961 lecture:
Most kinds of energy (with gravitational energy being a notable exception) are subject to strict local conservation laws as well. In this case, energy can only be exchanged between adjacent regions of space, and all observers agree as to the volumetric density of energy in any given space. There is also a global law of conservation of energy, stating that the total energy of the universe cannot change; this is a corollary of the local law, but not vice versa. The Laws of Thermodynamics. including careful definitions of energy, free energy, et cetera.
This law is a fundamental principle of physics. As shown rigorously by Noether's theorem, the conservation of energy is a mathematical consequence of translational symmetry of time, a property of most phenomena below the cosmic scale that makes them independent of their locations on the time coordinate. Put differently, yesterday, today, and tomorrow are physically indistinguishable. This is because energy is the quantity which is canonical conjugate to time. This mathematical entanglement of energy and time also results in the uncertainty principle – it is impossible to define the exact amount of energy during any definite time interval (though this is practically significant only for very short time intervals). The uncertainty principle should not be confused with energy conservation – rather it provides mathematical limits to which energy can in principle be defined and measured.
Each of the basic forces of nature is associated with a different type of potential energy, and all types of potential energy (like all other types of energy) appear as system mass, whenever present. For example, a compressed spring will be slightly more massive than before it was compressed. Likewise, whenever energy is transferred between systems by any mechanism, an associated mass is transferred with it.
In quantum mechanics energy is expressed using the Hamiltonian operator. On any time scale, the uncertainty in the energy is given by
In particle physics, this inequality permits a qualitative understanding of virtual particles, which carry momentum. The exchange of virtual particles with real particles is responsible for the creation of all known fundamental forces (more accurately known as fundamental interactions). Virtual photons are also responsible for the electrostatic interaction between (which results in Coulomb's law), for spontaneous radiative decay of excited atomic and nuclear states, for the Casimir force, for the Van der Waals force, and some other observable phenomena.
Energy is strictly conserved and is also locally conserved wherever it can be defined. In thermodynamics, for closed systems, the process of energy transfer is described by the first law:There are several sign conventions for this equation. Here, the signs in this equation follow the IUPAC convention.
where is the amount of energy transferred, represents the work done on or by the system, and represents the heat flow into or out of the system. As a simplification, the heat term, , can sometimes be ignored, especially for fast processes involving gases, which are poor conductors of heat, or when the thermal efficiency of the transfer is high. For such adiabatic processes,
This simplified equation is the one used to define the joule, for example.
This equation is highly specific, ignoring all chemical, electrical, nuclear, and gravitational forces, effects such as advection of any form of energy other than heat and PV-work. The general formulation of the first law (i.e., conservation of energy) is valid even in situations in which the system is not homogeneous. For these cases the change in internal energy of a closed system is expressed in a general form by:
This principle is vitally important to understanding the behavior of a quantity closely related to energy, called entropy. Entropy is a measure of evenness of a distribution of energy between parts of a system. When an isolated system is given more degrees of freedom (i.e., given new available that are the same as existing states), then total energy spreads over all available degrees equally without distinction between "new" and "old" degrees. This mathematical result is part of the second law of thermodynamics. The second law of thermodynamics is simple only for systems which are near or in a physical equilibrium state. For non-equilibrium systems, the laws governing the systems' behavior are still debatable. One of the guiding principles for these systems is the principle of maximum entropy production. It states that nonequilibrium systems behave in such a way as to maximize their entropy production.
Earth sciences
Cosmology
Quantum mechanics
Relativity
Transformation
+Some forms of Energy transfer of energy ("energy in transit") from one object or system to another
! Type of transfer process!! Description Heat equal amount of thermal energy in transit spontaneously towards a lower-temperature object Work equal amount of energy in transit due to a displacement in the direction of an applied force Transfer of material equal amount of energy carried by matter that is moving from one system to another
Conservation of energy and mass in transformation
Hence,
†:
Reversible and non-reversible transformations
Conservation of energy
which is similar in form to the Heisenberg Uncertainty Principle, but not really mathematically equivalent thereto, since E and t are not dynamically conjugate variables, neither in classical nor in quantum mechanics.
Energy transfer
Closed systems
Open systems
Thermodynamics
Internal energy
First law of thermodynamics
where the first term on the right is the heat transferred into the system, expressed in terms of temperature T and entropy S (in which entropy increases and its change d S is positive when heat is added to the system), and the last term on the right hand side is identified as work done on the system, where pressure is P and volume V (the negative sign results since compression of the system requires work to be done on it and so the volume change, d V, is negative when work is done on the system).
where is the heat supplied to the system and is the work applied to the system.
Equipartition of energy
See also
Notes
External links
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